肖晶,男,1987年生,博士,副教授,博士生导师。2016年博士毕业于湖南大学,2017年至2018年在日本产业技术综合研究所从事博士后研究工作。中国化学会会员,现为理论有机化学与功能分子教育部重点实验室专职科研人员。主要研究方向为绿色有机磷合成方法学和含磷精细化学品的绿色制备,近年来主持国家自然科学面上项目及基金青年项目2项、省部级项目2项、重点实验室开放课题2项,企业横向课题1项。在《Org. Lett.》、《Chem. Commun.》、《Adv. Synth. Catal.》以及《J. Org. Chem.》等国际主流期刊发表多篇论文,授权发明专利4项,并担任《Org. Lett.》、《Adv. Synth. Catal.》、《J. Org. Chem.》等期刊审稿人。
PS: 本人主打快乐而不失严谨的科研,师生和谐共处,亦师亦友,欢迎各位有志研究生加入课题组!
《有机化学》《有机化学实验》《环境保护概论》
[1] 国家自然科学基金面上项目,烯基噻蒽盐参与的光催化合成新型远端烯基磷酰化合物(22378107),50万,2024.01-2027.12
[2] 国家自然科学青年基金项目,铜催化C-H键活化与自由基介导构筑C-C键的反应研究(21703061),26万,2018.01-2020.12
[3] 湖南省自然科学青年基金,基于过渡金属催化C-O键活化的炔烃加成反应研究(2017JJ3081),5万,2017.01-2019.12
[4] 横向课题,基于亚磷酸的有机还原反应方法开发(D121L4), 20 万,2021.12-2023.12
[1] Jing Xiao*, Jie Wang, Huimin Zhang, Jianqiu Zhang, Li-Biao Han, Reduction of Triphenylphosphine Oxide to Triphenylphosphine by Phosphonic Acid, J. Org. Chem ., 2023, 88, 3909–3915.
[2] Jing Xiao*, Fengzhe Guo, Yinfeng Li, Fangshao Li, Qiang Li, Zi-Long Tang, Iodine Promoted Conversion of Esters to Nitriles and Ketones under Metal-Free Conditions, J. Org. Chem ., 2021, 86, 2028–2035.
[3] Fang Lv, Jing Xiao*, Junchun Xiang, Fengzhe Guo, Zi-Long Tang, Li-Biao Han*, Conversion of Aryl Aldehydes to Benzyl Iodides and Diarylmethanes by H3PO3/I2, J. Org. Chem ., 2021, 86, 3081–3088.
[4] Jing Xiao*, Fangshao Li, Ting Zhong, Xiaofang Wu, Fengzhe Guo, Qiang Li, Zi-Long Tang, Copper-catalyzed Radical Oxidative C(sp3)-H/C(sp3)-H Cross-coupling Between Arylacetonitriles and Benzylic Compounds, Tetrahedron , 2020, 76, 131621.
[5] Jing Xiao, Qiang Li, Ruwei Shen*, Shigeru Shimada, and Li-Biao Han*, Phosphonium Phenolate Zwitterion vs Phosphonium Ylide: Synthesis, Characterization and Reactivity Study of a Trimethylphosphonium Phenolate Zwitterion. Adv. Synth. Catal. , 2019, 361, 5715–5720.
[6] Jing Xiao*, Yonghao Ma, Xiaofang Wu, Jing Gao, Zilong Tang and Li-Biao Han*, Phosphonic Acid Mediated Practical Dehalogenation and Benzylation with Benzyl Halides. RSC Adv. , 2019, 9, 22343–22347.
[7] Jing Xiao and Li-Biao Han*, Ready Access to Organoiodides: Practical Hydroiodination and Doubleiodination of Carbon-Carbon Unsaturated Bonds with I2. Tetrahedron , 2019, 75, 3510–3515.
[8] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed α-Benzylation of Arylacetonitriles via C-O Activation. Adv. Synth. Catal. , 2016, 358, 816–819.
[9] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed Synthesis of (E)-Olefins from Benzylic Alcohol Derivatives and Arylacetonitriles via C-O Activation. Chem. Commun. , 2016, 52, 2157–2160.
[10] Jing, Xiao, Tieqiao Chen*, Li-Biao Han*, Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes. Org. Lett. , 2015, 17, 812–815.
[11] Jing Xiao, Qiang Li, Tieqiao Chen*, Li-Biao Han*, Copper-mediated Selective Aerobic Oxidative C3-cyanation of Indoles with DMF. Tetrahedron Lett. , 2015, 56, 5937–5940.
[12] Jing Xiao, Jia Yang, Tieqiao Chen*, Li-Biao Han*, Nickel-catalyzed α-benzylation of sulfones with esters via C−O activation. RSC Adv. , 2016, 6, 42656–42659.
[13] Jia Yang, Jing Xiao (Contributed equally), Tieqiao Chen*, Li-Biao Han*, Nickel-catalyzed phosphorylation of phenol derivatives via C−O/P−H cross-coupling. J. Org. Chem. , 2016, 81, 3911–3916.
绿色有机磷合成方法学;含磷精细化学品的绿色制备