刘秋华

  • 性 别:
  • 职称:副教授
  • 学 历:博士研究生
  • 学院:化学化工学院
  • 系部所:化学系
  • 执教层次:硕士生导师
  • 电话:
  • 电子邮箱:liuqiuhua@hnust.edu.cn

基本情况

刘秋华,女,1981年出生,博士,校聘教授,硕士研究生导师,化学化工学院化学系教师。2018年和2023年获得国家留学基金委资助分别赴美国和澳大利亚访问学者一年。主要从事生物无机化学和金属有机化学及相关的研究,围绕金属配合物功能分子的设计、合成、性能,以及相关组装体系开展了一系列研究工作。主持国家自然科学基金青年项目、湖南省教育厅重点科学研究项目湖南省自然科学基金面上项目、湖南省教育厅教研教改重点项目等项目。2022以第一完成人得湖南省自然科学奖三等奖。近年研究成果发表在《J. Am. Chem. Soc. 》、《Inorg. Chem.》、《Phys. Chem. C》、《Org. Biomol. Chem.》、《J. Phys. Chem. B》、《Org. Lett.》、《Chem. Eur. J.》、《Eur. J. Inorg. Chem. 》、《Chin. J. Chem》等权威学术刊物上。以第一发明人获得授权澳大利亚革新专利1项、国家发明专利3项。


承担课程

有机化学理论及实验课程、无机化学理论及实验课程等

主持课题

[1]湖南省自然科学基金面上项目, 核/壳型锡异佛咯啉的合成及其光催化烯烃的环氧化(2023JJ30225), 2023.01-2025.12;

[2]湖南省教育厅教研教改重点项目,现代信息技术与工科《有机化学》课程教学有机融合的探索与实践(HNJG-20230630),2023 .09 - 2027 .06 ;

[3] 国家自然科学基金青年项目,大环变形对卟啉中心钴(Ⅱ)离子电子结构的调控(No.21602054),20万,2017.01-2019.12,结题;

[4] 湖南省教育厅重点科学研究项目,碳纳米管管径和管长对其光谱红移影响的理论研究(No. 20A195),8万,2020.10-2023.09,在研

代表性论文

[1] Qiuhua Liu,* Junhao Gao, Qin Lin, Borong Liao, Qian Zhang, Zaichun Zhou,* Size‐ and Charge‐Matching Effect between Porphyrin Core and Central Metal on the Stability of Cuprous Ion, Applied Organometallic Chemistry, 2024, 38, e7318.

[2] Qiuhua Liu,* Junhao Gao, Yusheng Zhang, Xin Liu, Xi Zhang, Qin Lin, Wennan Zeng, Zaichun Zhou,* A Trans-Ortho Asymmetrically Di-Strapped Metalloporphyrin Integrating Three Key Structural Features of Ligand in Heme, Chinese Chemical Letters, 2023, 34, 108315.

[3] Qiuhua Liu, Wanjie Ren, Siwei Zhang, Yang Huang, Dilong Chen, Wennan Zeng, Zaichun Zhou,* Lin He,* Wenping Guo,* Jianfeng Li,* d-Orbital Reconstructions Forced by Double Bow-Shaped Deformations and Second Coordination Sphere Effects of Cu(II) Heme Analogs in HER, Chemistry-A European Journal, 2022, 28, e202103892.

[4] Qiuhua Liu,* Xiaorong Shen, Ye Dai, Mengchen Zhang, Zaichun Zhou,* Porous Materials Formed by Four Self-Construction Processes, Organic and Biomolecular Chemistry, 2022, 20, 8149-8156.

[5] Jinjin Zhang, Min Tang, Dilong Chen, Binghua Lin, Zaichun Zhou,* Qiuhua Liu,* Horizontal and Vertical Push Effects in Saddled Zinc Porphyrin Complexes: Implications for Heme Distortion, Inorganic Chemistry, 2019, 58, 2627−2636.

[6] Qiuhua Liu, Jinjin Zhang, Min Tang, Yan Yang, Jian Zhang,* Zaichun Zhou,* Geometric Deconstruction of Core and Electron Activation of a π-System in a Series of Deformed Porphyrins: Mimics of Heme, Organic & Biomolecular Chemistry, 2018, 16, 7725–7736.

[7] Jingzhi Lu, Brian Pattengale, Qiuhua Liu, Sizhuo Yang, Wenxiong Shi, Shuzhou Li,*Jier Huang,* Jian Zhang*, Donor−Acceptor Fluorophores for Energy-Transfer-Mediated Photocatalysis, Journal of the American Chemical Society, 2018, 140, 13719−13725.

[8] Min Tang, Yan Yang, Shaowei Zhang, Jiafu Chen, Jian Zhang, Zaichun Zhou,* Qiuhua Liu*, Electron Transfer and Geometric Conversion of Co−NO Moiety in Saddled Porphyrins: Implications for Trigger Role of Tetrapyrrole Distortion, Inorganic Chemistry, 2018, 57, 277−287.

[9] Qiuhua Liu, Min Tang, Wennan Zeng, Xi Zhang, Jianxiu Wang,* Zaichun Zhou*, Optimal Size Matching and Minimal Distortion Energy: Implications for Natural Selection by the Macrocycle of the Iron Species in Heme, Eur. J. Inorg. Chem. 2016, 5222–5229.

[10] Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou*, Origin of d-π Interaction in Cobalt(II) Porphyrins under Synergistic Effects of Core Contraction and Axial Ligation: Implications for a Ligand Effect of Natural Distorted Tetrapyrrole. Chin. J. Chem. 2016, 34, 910—918.

[11] Zaichun Zhou,* Min Tang, Qiuhua Liu,* Xi Zhang, Xiaochun Zhou, Formation of π-Cation Radicals in Highly Deformed Copper(II) Porphyrins: Implications for the Distortion of Natural Tetrapyrrole Macrocycles, Eur. J. Inorg. Chem. 2016, 3585–3591.

[12] Qiuhua Liu, Xiaochun Zhou, Haomin Liu, Xi Zhang, Zaichun Zhou*, Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+from Fe3+during the core contraction of macrocycles: implication for heme distortion. Org. Biomol. Chem., 2015, 13, 2939–2946.

[13] Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou*, Fine-Tuning of Electronic Structure of Cobalt(II) Ion in Nonplanar Porphyrins and Tracking of a Cross-Hybrid Stage: Implications for the Distortion of Natural Tetrapyrrole Macrocycles. J. Phys. Chem. B 2015, 119, 14102−14110.

[14] Zaichun Zhou*, Xiaochun Zhou, Qiuhua Liu,* Xizhang, Haomin Liu, Fixation of Zinc(II) Ion to Dioxygen in a Highly Deformed Porphyrin: Implications for the Oxygen Carrier Mechanism of Distorted Heme, Org. Lett. 2015, 17, 4078-4081.


奖励荣誉

[1]2022年湖南省自然科学奖三等奖,第一完成人

[2]2022年湖南科技大学教师信息化教学竞赛一等奖

[3]2022年湖南科技大学教学优良榜

专利成果

[1]刘秋华; 张思维; 唐敏; 周再春; 张金金; 杨艳; 一种相转移催化剂及其合成方法, 2022-2-18, 中 国, ZL 201711383674.4 

[2]刘秋华; 雷行; 周再春; 陈地龙; 林炳华; 一种铜卟啉催化剂及其复合材料的制备及应用, 2021-8- 31, 中国, ZL 202010556636.X  

[3]Qiuhua Liu; Huiyang Xu; Zaichun Zhou; Siwei Zhang ; Heme ligand mimetics and synthesis method, 2020-12-16, 澳大利亚革新专利, 2020103151 

[4]刘秋华; 唐敏; 周再春; 新型水溶性八羟基卟啉的一步合成方法, 2017-11-10, 中国, ZL 201510945703.6