彭丽芬

  • 性 别:
  • 职称:副教授
  • 学 历:博士研究生
  • 学院:化学化工学院
  • 系部所:教育部重点实验室
  • 执教层次:硕士生导师
  • 电话:
  • 电子邮箱:1060137@hnust.edu.cn

基本情况

彭丽芬,1985年12月生,副教授,硕士生导师。2004年9月至2008年6月在湖南大学获得学士学位;2008年9月至2011年6月在湖南大学获得化学硕士学位,导师:许新华教授;2011年9月至2014年9月在日本冈山理科大学获得博士学位,导师:Junzo Otera教授和Akihiro Orita教授;2014年10月至2015年10月在香港中文大学进行研究助理(博士后型)工作,合作导师:黄乃正院士;2015年10月至今在湖南科技大学理论有机化学与功能分子教育部重点实验室担任专职科研人员。主要从事有机金属催化方法学及复杂炔烃化合物合成的研究,主持国家青年基金、湖南省青年基金及省教育厅一般项目各1项,以第一作者或通讯作者SCI论文二十篇左右。

主持课题

[1]过渡金属催化硝基芳烃与末端炔烃交叉偶联构筑C(sp2)-C(sp)键的研究(国家青年基金,编号:21802040),25.5万元,2019.01-2021.12;

[2]四苯并环辛四烯胺类双核过渡金属配合物催化剂的设计合成及性能研究(湖南省青年基金,编号:2018JJ3145),5万元,2018.01-2020.12;

[3]端炔烃新型极性保护基的研究(湖南省教育厅一般项目,编号:17C0629),1万元,2017.01-2019.12;

[4]芳香炔豆素衍生物的合成及光学性质研究(重点实验室开放基金,编号:E21630),1.0万元,2016.01-2017.12。

[5]天然产物EGCG及其衍生物的全合成(横向项目),合同经费 50万元,2022年12月-2024年12月。

代表性论文

[1]Lifen Peng, Yanting Zhao, Yasuhiro Okuda, Liyuan Le, Zilong Tang, Shuang-Feng Yin, Renhua Qiu,* Akihiro Orita*, Process-Divergent Syntheses of 4- and 5-Sulfur-Functionalized 1,2,3-Triazoles via Copper-Catalyzed Azide-Alkyne Cycloadditions of 1-Phosphinyl-2-sulfanylethynes, J. Org. Chem. 2023, 88, 3089-3108.

[2]Hao Lu, Jiayi Chen, Wenjun Zhou, Lifen Peng,* Shuang-Feng Yin, Nobuaki Kambe, Renhua Qiu*, Selectfluor-Promoted Reactions of Aryl Methyl Ketones with Dimethyl Sulfoxide to Give 2,5-Diacylthiophenes and β‑Acyl Allylic Methylsulfones. Org. Lett. 2023, 25, 389−394.

[3]Lifen Peng, Yanting Zhao, Tianbao Yang, Zhou Tong, Zilong Tang*,  Akihiro Orita*, Renhua Qiu*, Zirconium‑Based Catalysts in Organic Synthesis. Topics Curr. Chem. 2022, 380, 41.

[4]Lingteng Peng, Zhifang Hu, Yanting Zhao, Lifen Peng*, Zhi Xu, Shuang-Feng Yin, Zilong Tang, Renhua Qiu*, Nobuaki Kambe*, One-pot synthesis of phosphorylnaphth[2,1-d] oxazoles and products as P,N-ligands in C–N and C–C formation. Org. Biomol. Chem., 2022, 20, 4110-4114.

[5]ZhifangHu,Lifen Peng,* Renhua Qiu, AkihiroOrita, Recent Progress of Protecting Groups for Terminal Alkynes, Chin. J. Org. Chem.2020, 40, 3112-3119.

[6]Li Wu, Lifen Peng,* Zhifang Hu, Yinchun Jiao, Zilong Tang, Xinhua Xu, Recent advances of sulfonylation reactions in water, Current organic synthesis 2020, 17, 271 - 281.

[7]PengLifen, HuZhifang, Wang Hong, WuLi, Jiao Yinchun, TangZilong,XuXinhua, Direct cyanation, hydrocyanation, dicyanation and cyanofunctionalization of alkynes, RSC Advance 2020, 10232-10244.

[8]Lifen Peng,* Zhifang Hu, QiChao Lu, Zilong Tang, YinChun Jiao, Xinhua Xu, DESs: Green solvents for transition metal catalyzed organic reactions, Chinese Chem. Lett.2019, 30, 2151-2156. (大型国际会议(日本大阪WCF2021, 2021年5月)受邀做报告论文)

[9]Lifen Peng,* Zhifang Hu, Zilong Tang, YinChun Jiao, Xinhua Xu, Recent progress in transition metal catalyzed cross coupling of nitroarenes, Chinese Chem. Lett.2019, 30, 1481-1487.

[10]Li Wu, Lifen Peng,* Zhifang Hu, Hong Wang, Zilong Tang, Yinchun Jiao, Xinhua Xu, Synthesis of cyclic phenyl hexayne from Me3Si-/Ph2P(O)-protected ethynes, Journal of chemical research2019, 43, 503-506.

[11]Lifen Peng,* Siwei Zhang, Binghao Wang, Mengshuo Xun, Zilong Tang, Yinchun Jiao, Xinhua Xu, Synthesis of cyclic phenyl polyynes: Ph2P(O)-deprotection/intramolecular Eglington coupling cyclization, Chin. J. Org. Chem.2018, 38, 519-525.

[12]Lifen Peng, Binghao Wang, Ming Wang, Zilong Tang, Yanzi Jiang, Yinchun Jiao, Xinhua Xu, A one-pot method for the synthesis of phenylalkynyl-substituted terminal alkynes by deprotection/stannylation followed by a Migita-Kosugi-Stille coupling, Journal of chemical research2018, 42, 235-238.

[13]Lifen Peng, Jiaying Lei, Li Wu, Zilong Tang, Zhipeng Luo, Yinchun Jiao, Xinhua Xu, One-pot transformation of Me3Si-/Ph2P(O)-protected ethynes to unsymmetrical arylethynes, Journal of chemical research2018, 42, 271-273.

[14]Lifen Peng,* Chao Peng, Ming Wang, Zilong Tang, Yinchun Jiao, Xinhua Xu, Phosphoryl protecting group enabled facile synthesis of unsymmetrical 1,3-diynes by selective Hay coupling, Chin. J. Org. Chem.2018, 38, 3048-3055.

[15]Lifen Peng, Rongzhen Li, Zilong Tang, Jingyang Chen, Rongnan Yi, Xinhua Xu, Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosuldes via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides, Tetrahedron2017, 73(22), 3099-3105.

[16]Lifen Peng,* Juan Jiang, Chao Peng, Ningning Dai, Zilong Tang, Yinchun Jiao, Jinyang Chen, Xinhua Xu, Synthesis of unsymmetrical aromatic acetylenes by diphenyl chlorophosphate-promoted condensation reaction of aromatic aldehydes and sulfones, Chin. J. Org. Chem. 2017, 37(11), 3013-3018.

[17]Zhi Tang, QiutTao Jiang, Lifen Peng, Xinhua Xu, Jie Li, Renhua Qiu, Chaktong Au.Zirconocene-catalyzed direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio under solvent-free conditions. Green Chem.2017, 19, 5396-5402.

[18]Lifen Peng, Feng Xu, Kenta Shinohara, Akihiro Orita, Junzo Otera. Remarkable electron-withdrawing effect of Ph2P(O)-ethynyl group: complete discrimination of ArBr vs ArI in Sonogashira coupling. Org. Chem. Front.2015, 2, 248-252.

[19]Lifen Peng, Feng Xu, Kenta Shinohara, Akihiro Orita, Junzo Otera. Selective deprotection of Me3Si-/Ph2P(O)-protected arylalkynes: Methyl Grignard reagent-promoted dephosphorylation of Ph2P(O)-protected alkynes. Chem. Lett.2014, 43(10), 1610-1612.

[20]Lifen Peng, Feng Xu, Yoshinori Suzuma, Akihiro Orita, Junzo Otera. One-pot transformation of Ph2P(O)-protected ethynes: deprotection followed by transition metal-catalyzed coupling. J. Org. Chem.2013, 78 (24), 12802-12808.

专利成果

[1]彭丽芬, 刘雨, 张思维, 付信亮, 李筱芳. 一种二芳基乙炔的合成方法: 中国, CN 106916047. 2017年07.

[2]彭丽芬, 廖凌燕, 赵文静, 唐子龙. 一种过渡金属催化硝基芳烃与末端芳基炔烃交叉偶联制备芳香炔烃的方法:中国, CN 108610225 A. 2018年10.