周再春,教授,硕士、博士研究生导师,南开大学化学博士毕业。
“理论有机化学与功能分子”教育部重点实验室和“分子设计与绿色化学”湖南省普通高校重点实验室专职研究人员。化学学科方向带头人之一,无机化学课程教学团队负责人。湖南省121人才工程(第三层次,2011)培养对象,第十二届湖南省化学化工学会理事。2017年留基委公派赴内布拉斯加大学•林肯分校进行访问研究。
现从事血红素化学、仿生催化以及超分子化学的研究。承担国家自然科学基金面上项目2项、教育部科学研究重点项目1项、湖南省自然科学基金、湖南省教育厅优秀青年项目、重点项目和创新平台项目等。完成湖南省自然科学奖1项;在《ChemSusChem》、《Chinese Chem. Lett.》、《Inorg. Chem.》、《Org. Lett.》、《Chem. Eur. J.》、《J. Phys. Chem. C》、《J. Phys. Chem. B》、《Org. Biomol. Chem.》和《Suf. Interfaces》等权威杂志上发表论文40余篇,得到近400次引用;已获得授权国家专利8项。十余次受邀在国际和全国性学术会议上贡献学术报告。
本科生课程:《无机化学》、《催化化学》、《高等有机化学》、《有机化学》、《文献检索与应用》
硕士研究生课程:《高等无机化学》、《化学前沿》
博士研究生课程:《现代储能材料》、《电化学前沿》
1.血红素中Fe-O2络合的顺磁性依赖(No. 201372069),国家自然科学基金面上项目,2014.01—2017.12
2.扭曲度可调型类血红素铁卟啉的合成及其复合物性能研究(No. 21071051),国家自然科学基金面上项目,2011.01—2013.12
3.非平面铁卟啉的合成及其催化氧化性能研究(No. 211121),教育部科学研究重点项目,2011.08—2013.12
(1) Borong Liao, Junhao Gao, Pei Weng, Linya He, Yusheng Zhang,* Qiuhua Liu,* Zaichun Zhou,* Semiconductor Effectfrom Pd(II) Porphyrin Metal to Its Ligand in Photocatalytic N-Dealkylation, ChemSusChem, 2025, 18, e202401381.
(2) Qiuhua Liu*, Junhao Gao, Qin Lin, Borong Liao, Qian Zhang, Zaichun Zhou*, Size- and Charge-Matching Effect Between Porphyrin Core and Central Metal on the Stability of Cuprous Ion, Appl. Organomet. Chem., 2024, 38(1): e7318.
(3) Qiuhua Liu, Chongchen Xiang, Qingxing Wu, Zaichun Zhou*, Yingping Zou, Wanqiang Liu*, Theoretical Exploration of the Molecular Stacking and Charge Transfer Mechanism of PBQx:Y6 OSCs, Surf. Interfaces, 2024, 44(1): 103767.
(4) Qiuhua Liu*, Junhao Gao, Yusheng Zhang, Xin Liu, Xi Zhang, Qin Lin, Wennan Zeng, Zaichun Zhou*, A trans-ortho Asymmetrically di-Strapped Metalloporphyrin Integrating Three Key Structural Features of Ligand In Heme, Chinese Chem. Lett., 2023, 34(10): 108315.
(5) Qiuhua Liu, Wanjie Ren, Siwei Zhang, Yang Huang, Dilong Chen, Wennan Zeng, Zaichun Zhou*, Lin He*, Wenping Guo*, Jianfeng Li*, d-Orbital Reconstructions Forced by Double Bow-Shaped Deformations and Second Coordination Sphere Effects of Cu(II) Heme Analogs in HER, Chem. Eur. J., 2022, 28(8): e202103892.
(6) Qiuhua Liu*, Xiaorong Shen, Ye Dai, Mengchen Zhang, Zaichun Zhou*, Porous Materials Formed by Four Self-Construction Processes, Org. Biomol. Chem., 2022, 20(41): 8149–8156.
(7) Jinjin Zhang, Min Tang, Dilong Chen, Binghua Lin, Zaichun Zhou*, Qiuhua Liu*, Horizontal and Vertical Push Effects in Saddled Zinc Porphyrin Complexes: Implications for Heme Distortion, Inorg. Chem., 2019, 58(4): 2627–2636.
(8) Brian Pattengale, Qiuhua Liu, Wenhui Hu, Sizhuo Yang, Peilei He, Sir Lawrence Tender, Yingqi Wang, Xiaoyi Zhang, Zaichun Zhou*, Jian Zhang*, Jier Huang*, Selective Excited State Dynamics in a Unique Set of Rationally Designed Ni Porphyrins, J. Phys. Chem. C, 2019, 123(29): 17994–18000.
(9) Min Tang, Yan Yang, Shaowei Zhang, Jiafu Chen, Jian Zhang, Zaichun Zhou*, Qiuhua Liu*, Electron Transfer and Geometric Conversion of Co−NO Moiety in Saddled Porphyrins: Implications for Trigger Role of Tetrapyrrole Distortion, Inorg. Chem., 2018, 57(1): 277–287.
(10) Qiuhua Liu, Jinjin Zhang, Min Tang, Yan Yang, Jian Zhang*, Zaichun Zhou*, Geometric Deconstruction of Core and Electron Activation of a π-System in a Series of Deformed Porphyrins: Mimics of Heme, Org. Biomol. Chem., 2018, 16(41): 7725–7736.
(11) Min Tang, Yan Yang, Shaowei Zhang, Jiafu Chen, Jian Zhang, Zaichun Zhou,* Qiuhua Liu,* Electron Transfer and Geometric Conversion of Co−NO Moiety in Saddled Porphyrins: Implications for Trigger Role of Tetrapyrrole Distortion, Inorg. Chem., 2018, 57(1): 277–287.
(12) Zaichun Zhou,* Xiaochun Zhou, Qiuhua Liu,* Xi Zhang, Haomin Liu, Fixation of Zinc(II) Ion to Dioxygen in a Highly Deformed Porphyrin: Implications for the Oxygen Carrier Mechanism of Distorted Heme, Org. Lett., 2015, 17(16): 4078–4081.
(13) Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou,* Fine-Tuning of Electronic Structure of Cobalt(II) Ion in Nonplanar Porphyrins and Tracking of a Cross-hybrid Stage: Implications for the Distortion of Natural Tetrapyrrole Macrocycles, J. Phys. Chem. B,2015, 119(44): 14102–14110.
(14) Qiuhua Liu, Xiaochun Zhou, Haomin Liu, Xi Zhang, Zaichun Zhou,*Fractional Transfer of a Free Unpaired Electron to Overcome Energy Barriers in the Formation of Fe4+ from Fe3+ during Core Contraction of Macrocycles: Implication for Heme Distortion, Org. Biomol. Chem., 2015, 13(10): 2939–2946.
(15) Zaichun Zhou,* Xi Zhang, Qiuhua Liu,* Ziqiang Yan, Chengjin Lv,Ge Long, Geometry and Temperature Dependence of meso-Aryl Rotation in Strained Metalloporphyrins: Adjustable Turnstile Molecules, Inorg. Chem., 2013, 52(18): 10258–10263.
(16) Zaichun Zhou,* Qiuhua Liu, Ziqiang Yan, Ge Long, Xi Zhang, Chenzhong Cao,* Rongqing Jiang, Conversion of Electron Configuration of Iron Ion through Core Contraction of Porphyrin: Implications for Heme Distortion, Org. Lett., 2013, 15(3): 606–609.
(17) Zaichun Zhou,* Min Shen, Chenzhong Cao, Qiuhua Liu, Ziqiang Yan, The Opposing Influences of Ruffling and Doming Deformation on the 4-N Cavity Size of Porphyrin Macorcycles: the Role of Heme Deformations Revealed, Chem. Eur. J., 2012, 18(25): 7675–7679.
(18) Yinchun Jiao, ChenzhongCao,* Zaichun Zhou, Direct Synthesis of anti-1,3-Diols through Nonclassical Reaction of Aryl Grignard Reagents with Isopropenyl Acetate, Org. Lett., 2011, 13(2): 180–183.
(19) Zaichun Zhou, Chenzhong Cao,* Qiuhua Liu, Rongqing Jiang, Hybrid Orbital Deformation (HOD) Effect and Spectral Red-Shift Property of Nonplanar porphyrin, Org. Lett., 2010, 12(8):1780–1783.
(20) Zaichun Zhou, Chenzhong Cao,* Zhiqing Yin, Qiuhua Liu, Bis(zinc porphyrin) Bridged by Benzo Orthocarbonates as a Conformational Switch under Regulation of DABCO and a Cu+ Ion, Org. Lett., 2009, 11(8):1781–1784.
学术报告
(1) Zaichun Zhou, etc, “Semiconductor effect of Pd(II) porphyrin in photocatalytic dealkylation” (invited report), First International Symposium on African Sustainability Energy Solutions, Suncity, South Africa, 2024.8.22‒2024.8.31
(2)“Hybrid Crossover of Metals in Nonplanar Porphyrin Series: from Concept to Application” (invited report),The First Asian Conference on Porphyrins, Phthalocyanines, and Related Materials (ACPP-1) & The Sixth National Conference on Porphyrins, Phthalocyanines, and Related Materials (NCPP-6), University of Chinese Academy of Sciences (Beijing), 2019.8.23–2019.8.26
(3)《非平面金属卟啉的合成及其对金属结构的调节》,中国化学会第十六届全国有机合成化学学术研讨会,河南大学(开封),2019.8.8–2019.8.11
(4)《从化学键角度判断NO在金属上的转变》(邀请报告),中国化学会第三届全国化学键及应用学术研讨会,中科院工程物理研究所(绵阳),2017.8.22–2017.8.24
(5)《血红素对铁的选择和氧活化》(邀请报告),中国化学会第30届化学年会,大连理工大学(大连),2016.7.1–2016.7.4
(6)《交叉杂化(Cross-hybrid)理论的成型和意义》(邀请报告),中国化学会第十一届全国物理有机化学学术会议,清华大学(北京),2015.9.18–2015.9.21
(7)《高度扭曲金属卟啉对分子氧的固定》,中国化学会第九届全国有机化学学术会议,东北师范大学(长春),2015.7.28–2015.8.1
(8)《键变形的产生和性能——机械化学》(邀请报告),中国化学会第二届全学键及应用术研讨会,南开大学(天津),2014.7.19–2014.07.21
(9)《非平面卟啉核收缩对高价钴的稳定作用》,中国化学会第八届全国有机化学学术会议,西南大学(重庆),2013.10.17–2013.10.21
(10)《血红素大环扭曲的功能及模拟》,中国化学会第七届全国有机化学学术会议,南京大学(南京),2011.11.12–2011.11.15
刘秋华、周再春、王建秀、曾文南、张茜,类血红素复合物中配体的变构效应及规律研究,湖南省自然科学三等奖,湖南省人民政府,2022年。
(1) 周再春、张梦臣、张金金、刘秋华,一类基于环聚物折叠和组装的框架分子及其制备方法,中国专利,ZL 2018115995190,2021年12月03日授权。
(2) 周再春、陈地龙、刘秋华,2,2',6,6'-四羧基-[4,4'-联吡啶]的合成方法,中国专利,ZL 2018115995063,2021年10月08日授权。
(3) 刘秋华、雷行、周再春、陈地龙、林炳华,一种铜卟啉催化剂及其复合材料的制备及应用,中国专利,ZL 202010556636X,2021年08月31日授权。
(4) Qiuhua Liu, Huiyang Xu, Zaichun Zhou, Siwei Zhang, Heme Ligand Mimetics and Synthesis Method, 澳大利亚革新专利, 2020103151,2020年12月30日授权。
1. 仿生催化——不饱和小分子活化和惰性C-H键活化
2. 生物无机化学——血红素结构和功能的模拟
3. 超分子化学——共价有机框架(COF)材料的设计与合成