周再春，教授，博士研究生导师，南开大学博士毕业。“理论有机化学与功能分子”教育部重点实验室和“分子构效关系”湖南省普通高校重点实验室专职研究人员。化学学科方向学术带头人之一。2011年湖南省121人才（第三层次）工程培养对象，第十二届湖南省化学化工学会理事。2017年留基委公派赴内布拉斯加大学•林肯分校进行访问研究。

现从事血红素化学、仿生催化以及共价有机框架材料的研究。近年来，承担国家自然科学基金面上项目、教育部科学研究重点项目、教育厅普通高校青年项目和创新平台项目等。在《Inorg. Chem.》、《Org. Lett.》、《Chem. Eur. J.》、《J. Phys. Chem. C》、《J. Phys. Chem. B》、《Org. Biomol. Chem.》和《Eur. J. Inorg. Chem.》等权威杂志上发表论文20余篇，得到近200次引用；已获得授权国家专利3项。多次受邀在全国性学术会议上贡献学术报告。

1.血红素中Fe-O2络合的顺磁性依赖（No. 201372069），国家自然科学基金面上项目，2014.01—2017.12

2.扭曲度可调型类血红素铁卟啉的合成及其复合物性能研究（No. 21071051），国家自然科学基金面上项目，2011.01—2013.12

3.非平面铁卟啉的合成及其催化氧化性能研究（No. 211121），教育部科学研究重点项目，2011.08—2013.12

(1)Jinjin Zhang, Min Tang, Dilong Chen, Binghua Lin, Zaichun Zhou,* Qiuhua Liu,* Horizontal and Vertical Push Effects in Saddled Zinc Porphyrin Complexes: Implications for Heme Distortion,Inorg. Chem.,2019, 58(4): 2627–2636.

(2)Brian Pattengale, Qiuhua Liu, Wenhui Hu, Sizhuo Yang, Peilei He, Sir Lawrence Tender, Yingqi Wang, Xiaoyi Zhang, Zaichun Zhou,* Jian Zhang,* Jier Huang,* Selective Excited State Dynamics in a Unique Set of Rationally Designed Ni Porphyrins, J. Phys. Chem. C, 2019, 123(29): 17994–18000.

(3)Qiuhua Liu, Jinjin Zhang, Min Tang, Yan Yang, Jian Zhang,*Zaichun Zhou,*Geometric Deconstruction of Core and Electron Activation of a π-System in a Series of Deformed Porphyrins: Mimics of Heme, Org. Biomol. Chem., 2018,16(41): 7725–7736.

(4)Min Tang, Yan Yang, Shaowei Zhang, Jiafu Chen, Jian Zhang, Zaichun Zhou,* Qiuhua Liu,* Electron Transfer and Geometric Conversion of Co−NO Moiety in Saddled Porphyrins: Implications for Trigger Role of Tetrapyrrole Distortion, Inorg. Chem., 2018, 57(1): 277–287.

(5)Zaichun Zhou,*Min Tang，Qiuhua Liu,* Xi Zhang，Xiaochun Zhou, Formation of π-Cation Radicals in Highly Deformed Copper(II) Porphyrins: Implications for the Distortion of Natural Tetrapyrrole Macrocycles, Eur. J. Inorg. Chem., 2016, 2016(22): 3583–3591.

(6)Qiuhua Liu, Min Tang, Wennan Zeng, Xi Zhang, Jianxiu Wang,* Zaichun Zhou,* Optimal Size Matching andMinimal Distortion Energy: Implications for Natural Selection bythe Macrocycleof the Iron Species in Heme, Eur. J. Inorg. Chem., 2016, 2016(33): 5222–5229.

(7)Zaichun Zhou,* Xiaochun Zhou, Qiuhua Liu,* Xi Zhang, Haomin Liu, Fixation of Zinc(II) Ion to Dioxygen in a Highly Deformed Porphyrin: Implications for the Oxygen Carrier Mechanism of Distorted Heme, Org. Lett., 2015, 17(16): 4078–4081.

(8)Qiuhua Liu, Xi Zhang, Wennan Zeng, Jianxiu Wang,* Zaichun Zhou,* Fine-Tuning of Electronic Structure of Cobalt(II) Ion in Nonplanar Porphyrins and Tracking of a Cross-hybrid Stage: Implications for the Distortion of Natural Tetrapyrrole Macrocycles, J. Phys. Chem. B,2015, 119(44): 14102–14110.

(9)Qiuhua Liu, Xiaochun Zhou, Haomin Liu, Xi Zhang, Zaichun Zhou,*Fractional Transfer of a Free Unpaired Electron to Overcome Energy Barriers in the Formation of Fe4+ from Fe3+ during Core Contraction of Macrocycles: Implication for Heme Distortion, Org. Biomol. Chem., 2015, 13(10): 2939–2946.

(10)Zaichun Zhou,* Xi Zhang, Qiuhua Liu,* Ziqiang Yan, Chengjin Lv,Ge Long, Geometry and Temperature Dependence of meso-Aryl Rotation in Strained Metalloporphyrins: Adjustable Turnstile Molecules, Inorg. Chem., 2013, 52(18): 10258–10263.

(11)Zaichun Zhou,* Qiuhua Liu, Ziqiang Yan, Ge Long, Xi Zhang, Chenzhong Cao,* Rongqing Jiang, Conversion of Electron Configuration of Iron Ion through Core Contraction of Porphyrin: Implications for Heme Distortion, Org. Lett., 2013, 15(3): 606–609.

(12)Zaichun Zhou,* Min Shen, Chenzhong Cao, Qiuhua Liu, Ziqiang Yan, The Opposing Influences of Ruffling and Doming Deformation on the 4-N Cavity Size of Porphyrin Macorcycles: the Role of Heme Deformations Revealed, Chem. Eur. J., 2012, 18(25): 7675–7679.

(13)Yinchun Jiao, ChenzhongCao,* Zaichun Zhou, Direct Synthesis of anti-1,3-Diols through Nonclassical Reaction of Aryl Grignard Reagents with Isopropenyl Acetate, Org. Lett., 2011, 13(2): 180–183.

(14)Zaichun Zhou, Chenzhong Cao,* Qiuhua Liu, Rongqing Jiang, Hybrid Orbital Deformation (HOD) Effect and Spectral Red-Shift Property of Nonplanar porphyrin, Org. Lett., 2010, 12(8):1780–1783.

(15)Zaichun Zhou, Chenzhong Cao,* Zhiqing Yin, Qiuhua Liu, Bis(zinc porphyrin) Bridged by Benzo Orthocarbonates as a Conformational Switch under Regulation of DABCO and a Cu+ Ion, Org. Lett., 2009, 11(8):1781–1784.

学术报告

(1)“Hybrid Crossover of Metals in Nonplanar Porphyrin Series: from Concept to Application” (invited report),The First Asian Conference on Porphyrins, Phthalocyanines, and Related Materials (ACPP-1) & The Sixth National Conference on Porphyrins, Phthalocyanines, and Related Materials (NCPP-6), University of Chinese Academy of Sciences (Beijing), 2019.8.23–2019.8.26

(2)《非平面金属卟啉的合成及其对金属结构的调节》，中国化学会第十六届全国有机合成化学学术研讨会，河南大学（开封），2019.8.8–2019.8.11

(3)《从化学键角度判断NO在金属上的转变》（邀请报告），中国化学会第三届全国化学键及应用学术研讨会，中科院工程物理研究所（绵阳），2017.8.22–2017.8.24

(4)《血红素对铁的选择和氧活化》（邀请报告），中国化学会第30届化学年会，大连理工大学（大连），2016.7.1–2016.7.4

(5)《交叉杂化(Cross-hybrid)理论的成型和意义》（邀请报告），中国化学会第十一届全国物理有机化学学术会议，清华大学（北京），2015.9.18–2015.9.21

(6)《高度扭曲金属卟啉对分子氧的固定》，中国化学会第九届全国有机化学学术会议，东北师范大学（长春），2015.7.28–2015.8.1

(7)《键变形的产生和性能——机械化学》（邀请报告），中国化学会第二届全学键及应用术研讨会，南开大学（天津），2014.7.19–2014.07.21

(8)《非平面卟啉核收缩对高价钴的稳定作用》，中国化学会第八届全国有机化学学术会议，西南大学（重庆），2013.10.17–2013.10.21

(9)《血红素大环扭曲的功能及模拟》，中国化学会第七届全国有机化学学术会议，南京大学（南京），2011.11.12–2011.11.15

(1)周再春，唐敏，刘秋华, 电压梯度法检测气体中痕量组分的方法, 2017. 7. 4, 中国，ZL201510945811.3

(2)刘秋华，唐敏，周再春, 新型水溶性八羟基卟啉的一步合成方法, 2017. 11. 10, 中国，ZL201510945703.6

(3)周再春，成奋民，马金辉，袁晟, 食品中挥发性N-亚硝胺类化合物的全检测方法, 2016. 4. 6, 中国，ZL201410321720.8

1. 仿生催化——不饱和小分子活化和惰性C-H键活化

2. 生物无机化学——血红素结构和功能的模拟

3. 超分子化学——共价有机框架（COF）材料的设计与合成