郑柏树

  • 性 别:
  • 职称:教授
  • 学 历:博士研究生
  • 学院:化学化工学院
  • 系部所:应用化学系
  • 执教层次:博士生导师
  • 电话:
  • 电子邮箱:zbaishu@163.com

基本情况

郑柏树,男,1978年生,博士,教授,博士生导师,现任化学化工学院副院长,湖南省化学化工学会理事。2011年毕业于南京大学配位化学国家重点实验室,首届唐敖庆化学奖学金获得者。目前主要从事分子间弱相互作用理论计算、功能多孔材料设计合成以及能源环境相关气体吸附存储分离、多相催化等研究。先后主持国家自然科学基金2项,湖南省自然科学基金和企业产学研等科研项目5项。首次成功将酰胺基、草酰胺基等极性桥连基修饰到孔结构稳定的高比表面MOFs材料中,为定向设计合成新型高性能MOFs储气、催化材料提供了新思路。已在《J. Am. Chem. Soc.》、《Chem. Commun.》、《Inorg. Chem.》、《Dalton Trans.》、《Inorg. Chem. Front.》、《ChemCatChem》、《ACS Sustainable Chem. Eng.》等国际重要学术刊物上发表SCI论文50余篇,被《Chem. Soc. Rev.》、《Chem. Rev.》《Coord. Chem. Rev.》等期刊引用1000余次。获湖南省自然科学奖、湖南省教学成果奖三等奖各1项(排名第六、第四)。授权中国发明专利5件,主编高等教育十二五规划教材1部。

学习经历

[1] 2008-09 2011-12, 南京大学, 化学, 博士

[2] 2001-09 2004-06, 贵州大学, 物理化学, 硕士

[3] 1997-09 2001-06, 湘潭工学院, 化学工程与工艺, 学士

工作经历

[1] 2019-12 , 湖南科技大学, 化学化工学院, 教授

[2] 2014-01 2019-11, 湖南科技大学, 化学化工学院, 副教授

[3] 2007-01 2013-12, 湖南科技大学, 化学化工学院, 讲师

[4] 2004-09 2006-12, 湖南科技大学, 化学化工学院, 助教

承担课程

本科生《物理化学》、《计算机在化学中的应用》、《物理化学实验》;

硕士生《高等物理化学》、《化学学科前沿讲座》;

博士生《现代催化化学》

主持课题

[1] 国家自然科学基金面上项目,功能性桥连基修饰MOF材料的可控合成、CO2吸附与催化转化性能研究(21973029),66.0万,2020.01-2023.12

[2] 国家自然科学基金青年项目,酰胺功能基修饰多孔配位聚合物的设计、合成与二氧化碳气体吸附性能研究(21201062),23.0万,2013.01-2015.12

[3] 湖南省自然科学基金面上项目,高性能储气脲基MOFs材料的合成与构效关系研究(2018JJ211),5.0万,2018.01-2020.12

[4] 湖南省自然科学基金青年项目,高孔隙率MOFs的定向构筑与H2、CO2气体吸附性能研究(14JJ3113),4.0万,2014.01-2016.12

[5] 企业横向项目,高纯硫酸锰精制技术开发(D11779),65.0万,2017.12-2018.12

[6] 南京大学配位化学国家重点实验室开放课题,(3, 12)-连接MOFs的设计合成与H2、CO2气体吸附性能研究(SKLCC1417),3.0万,2014.01-2015.12

[7] 湖南省普通高等学校教学改革研究项目,制药工程专业人才培养模式改革研究与实践(G21506),2.0万,2016.01-2018.12



代表性论文

[1] B. S. Zheng, J. F. Bai*, J. G. Duan, L. Wojtas and M. J. Zaworotko*, Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups, J. Am. Chem. Soc., 2011, 133, 748-751.

[2] B. S. Zheng, Z. Yang, J. F. Bai*, Y. Z. Li and S. H. Li*, High and selective CO2 capture by two mesoporous acylamide-functionalized rht-type metal-organic frameworks, Chem. Commun., 2012, 48, 7025-7027.

[3] B. S Zheng, H. T. Liu, Z. X. Wang*, X. Y. Yu*, P. G. Yi and J. F. Bai*, porous NbO-type metal–organic framework with inserted acylamide groups exhibiting highly selective CO2 capture, CrystEngComm, 2013, 16, 3517-3520.

[4] Z. X. Wang, B. S. Zheng*, H. T. Liu, X. Lin, X. Y. Yu, P. G. Yi and R. R. Yun*, High-capacity gas storage by a microporous oxalamide-functionalized NbO-type metal-organic framework, Cryst. Growth Des., 2013, 13, 5001-5006.

[5] B. S. Zheng*, R. R. Yun, J. F. Bai*, Z. Y. Lu, L. T. Du and Y. Z. Li, Expanded porous MOF-505 analogue exhibiting large hydrogen storage capacity and selective carbon dioxide adsorption, Inorg. Chem., 2013, 52, 2823-2829.

[6] Z. X. Wang, B. S. Zheng*, H. T. Liu, P. G. Yi, X. F. Li, X. Y. Yu* and R. R. Yun*, A highly porous 4,4-paddlewheel-connected NbO-type metal-organic framework with a large gas-uptake capacity, Dalton Trans., 2013, 42, 11304-11311.

[7] X. Y. Yu*, Q. Yao, H. W. Tao, Y. Yang, L. Li, B. S. Zheng*, S. Z. Zhu, A study on the interaction between 3-spiro-piperidones and bovine serum albumin using spectroscopic approaches, Luminescence, 2013, 28, 705-712.

[8] B. S. Zheng, B. Hou. Z. X. Wang*, P. G. Yi, J. Y. Wu*, X. L. Ding*, Theoretical characters and nature of the intermolecular lithium bonded interactions BLiCN/LiNC (B = pyridine, furan and thiophene), Compt. Theor. Chem., 2013, 1017, 153-158.

[9] B. S. Zheng, L. Deng, H. T. Liu, X. Y. Yu*, Z. X. Wang, X. C. Yang and P. G. Yi*, NMR and theoretical study on the coordination interactions between peroxovanadium(V) complex and bisubstituted pyridine ligands, J. Coord. Chem., 2013, 66(14), 2558-2566.

[10] B. S. Zheng*, X. Lin, Z. X. Wang*, R. R. Yun, Y. P. Fan, M. S. Ding, X. L. Hu and P. G. Yi*, Enhanced water stability of a microporous acylamide-functionalized metal-organic framework via interpenetration and methyl decoration, CrystEngComm, 2014, 16, 9586-9589.    

[11] L. T. Du, S. L. Yang, L. Xu*, H. H. Min and B. S. Zheng*, Highly selective carbon dioxide uptake by a microporous kgm-pillared metal-organic framework with acylamide groups, CrystEngComm, 2014, 16, 5520-5523.

[12] R. R. Yun*, R. R. Cui, F. J. Qian, X. Y. Cao, S. L. Luo and B. S. Zheng*, Formation of a metal-organic framework with high gas uptakes based upon amino-decorated polyhedral cages, RSC Adv., 2015, 5, 2374-2377.

[13] B. S. Zheng*, H. Wang, Z. X. Wang*, N. Ozaki, C. Hang, X. Luo, L. Huang, W. J. Zeng, M. Yang and J. G. Duan*, A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities, Chem. Commun., 2016, 52, 12988-12991.

[14] B. S. Zheng*, L. Huang, X. Y. Cao, S. H. Shen, H. F. Cao, C. Hang, W. J. Zeng and Z. X. Wang*, A highly porous acylamide decorated MOF-505 analogue exhibiting large and selective CO2 gas uptake capability, CrystEngComm, 2018, 20, 1874-1881.

[15] Z. X. Wang, X. Luo, B. S. Zheng*, L. Huang, C. Hang, Y. C. Jiao, X. Y. Cao, W. J. Zeng and R. R. Yun*, Highly selective carbon dioxide capture and cooperative catalysis of a water-stable acylamide-functionalized metal-organic framework, Eur. J. Inorg. Chem., 2018, 1309-1314.

[16] B. S. Zheng, X. Luo, Z. X. Wang*, S. W. Zhang, R. R. Yun*, L. Huang, W. J. Zeng and W. L. Liu*, An unprecedented water stable acylamide-functionalized metal-organic framework for highly efficient CH4/CO2 gas storage/separation and acid-base cooperative catalytic activity, Inorg. Chem. Front., 2018, 5, 2355-2363.

[17] B. S. Zheng, Y. Liu, Z. X. Wang*, F. X. Zhou, Y. C. Jiao*, Y. Liu, X. L. Ding* and Q. Z. Li, Comparison of halide donators based on pi···M (M = Cu, Ag, Au), pi···H and pi···halogen bonds, Theor. Chem. Acc., 2018, 137, 179. https://doi.org/10.1007/s00214-018-2390-1.

[18] B. S. Zheng, Y. Liu, L. Huang, Z. X. Wang*, H. X. Liu and Y. Liu*, Cooperative effects between F ··· Ag bonded and X ···Br (Cl) halogen-bonded interaction in BrF(ClF) ···AgX ··· BrF(ClF) (X = F, Cl, Br) complexes: a theoretical study, Mol. Phys., 2018, 1834-1843.

[19] R. R. Yun*, L. R. Hong, W. J. Ma, W. G. Jia, S. J. Liu* and B. S. Zheng*, Fe/Fe2O3@N-dopped porous carbon: a high-performance catalyst for selective hydrogenation of nitro compounds, ChemCatChem, 2019, 2, 724-728.

[20] R. R. Yun*, L. R. Hong, W. J. Ma, S. N. Wang*, and B. S. Zheng*, Nitrogen-rich porous carbon-stabilized Ni-Co nanoparticles for the hydrogenation of quinolines, ACS Appl. Nano Mater., 2019, 2, 6763-6768.

[21] F. X. Zhou, Y. Liu, Z. X. Wang*, T. Lu, Q. Y. Yang*, Y. Liu and B. S. Zheng*, A new type of halogen bond involving multivalent astatine: an ab initio study, Phys. Chem. Chem. Phys., 2019, 21, 15310-15318.

[22] R. R. Yun*, W. J. Ma, L. R. Hong, Y. Hu, F. Zhan, S. Liu and B. S. Zheng*, Ni@PC as a stabilized catalyst toward efficient hydrogenation of quinoline under ambient temperature, Catal. Sci. Technol., 2019, 9, 6669-6672.

[23] B. S. Zheng, F. X. Zhou, Y. Liu, Z. X. Wang*, Y. Liu* and X. L. Ding, Halogen bonds and metal bonds involving superalkalies M2OCN/M2NCO (M = Li, Na) complexes, Struct. Chem., 2019, 30, 965-977.

[24] B. S. Zheng, Y. Liu, Z. X. Wang*, F. X. Zhou, Y. Liu, X. L. Ding* and T. Lu, Regium bonds formed by MX (M=Cu, Ag, Au; X=F, Cl, Br) with phosphine-oxide/phosphinous acid: comparisons between oxygen-shared and phosphine-shared complexes, Mol. Phys., 2019, 2443-2455.

[25] J. X. Liao, W. J. Zeng, B. S. Zheng*, X. Y. Cao, Z. X. Wang*, G. Y. Wang and Q. Y. Yang*, Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal-organic framework, Inorg. Chem. Front., 2020, 7, 1939-1948.

[26] R. R. Yun*, Z. W. Ma, Y. Hu, F. Y. Zhan, C. Qiu, B. S. Zheng*, T. Sheng*, Nano-Ni-MOFs: high active catalysts on the cascade hydrogenation of quinolines, Catal. Lett., 2021, 151, 2445-2451.

[27] 王莹, 郑柏树*, 王刘盛, 汪冠宇, 曾文江, 汪朝旭, 阳庆元*. 锆基金属-有机骨架材料分离放射性气体Rn的计算筛选研究, 化工学报, 2021, 72(5), 2688-2696.

[28] Y. Wang, G. Y. Wang, Y. Liu, B. S. Zheng*, Z. X. Wang*, and Q. Y. Yang*, Identifying promising covalent-organic frameworks for decarburization and desulfurization from biogas via computational screening, ACS Sustainable Chem. Eng., 2021, 9, 8858-8867.

[29] R. R. Yun*, B. B. Zhang, C. Qiu, Z. W. Ma, F. Y. Zhan, T. Sheng*, and B. S. Zheng*, Encapsulating cobalt into N-doping hollow frameworks for efficient cascade catalysis, Inorg. Chem., 2021, 60(13), 9757-9761.

[30] R. R. Yun,* B. B. Zhang, F. Y. Zhan, L. T. Du, Z. X. Wang*, and B. S. Zheng*, Cu nanoclusters anchored on the metal-organic framework for the hydrolysis of ammonia borane and the reduction of quinolines, Inorg. Chem., 2021, 60(13), 12906-12911.

[31] W. J. Zeng, G. Y. Wang, B. S. Zheng*, Z. X. Wang and J. F. Bai*, A porous amide-functionalized pto-type MOF exhibiting selective capture and separation of cationic MB dye, J. Coord. Chem., 2021, 74(1-3), 241-251.

[32] L. T. Du, Y. C. Miao, B. S. Zheng*, M. T. Ma, J. C. Zhang*, Honeycomb-like 2D metal-organic polyhedral framework exhibiting selectively adsorption of CO2, J. Solid State Chem., 2021, 300,122230.

[33] Z. Y. Shen, L. R. Hong, B. S. Zheng*, G. Y. Wang, B. B. Zhang, Z. X. Wang*, F. Y. Zhan, S. H. Shen and R. R. Yun*, Highly efficient and chemo-selective hydrogenation of nitro compounds into amines by nitrogen-doped porous carbon supported Co/Ni bimetallic nanoparticles, Inorg. Chem., 2021, 60, 16834-16839.

[34] G. Y. Wang, Z. X. Wang*, W. L. Cao, Y. Liu, B. S. Zheng*, Y. Q. Deng*, Identifying promising covalent organic frameworks for HCHO/O2+N2 adsorption from indoor air pollution using high-throughput computational screening, Compt. Theor. Chem., 2022, 1210, 113655.

[35] F. G. Xu, F. Y. Zhan, B. B. Zhang, T. H. Li, L. He, L. T. Du, S. Z. Luo*, B. S. Zheng*, R. R. Yun*, A pod-like core-shell catalyst with high reduction performance under mild conditions, Eur. J. Inorg. Chem., 2022, e202100996.

[36] Y. S Jiang, Z. Zhang, W. L. Cao, B. S. Zheng*, Z. X. Wang*  and R. R. Yun*, Iron-based active sites encapsulated in carbon nanotubes for efficient hydride process, ACS Appl. Nano Mater., 2023, 6(5), 3218-3225.

[37] Z. Zhang, Y. Liu, J. F. Du, Y. S. Jiang, Z. X. Wang,* R. R. Yun*and B. S. Zheng*, Highly efficient hydrogenation of nitroarenes by Co nanoparticles encapsulated in N-doped carbon nanotubes under mild conditions, Inorg. Chem. Front., 2023, 10, 7028-7037. 



科研成果

出版教材或专著:

[1] 易平贵,郑柏树主编. 物理化学实验,中国矿业大学出版社,2013年。


专利成果

[1] 郑柏树、张维,一种高精度检测挥发性有机化合物的检测方法,ZL 2020 10319903.1

[2] 郑柏树、汪冠宇、王莹、廖俊雄、汪朝旭、张少伟,氨基桥连六羧酸配体和金属有机框架材料及其制备方法和应用,ZL 202110019307.6

[3] 汪朝旭、王莹、汪冠宇、郑柏树、曹喜洋、曾文江、刘秋华,酰胺基桥连六羧酸配体和金属有机框架材料及其制备方法和应用,ZL 202110018716.4

[4] 曾坚贤,董志辉,郑柏树,周虎,吕超强,曾杰辉,马溢昌,一种钨酸根离子印迹陶瓷膜的制备方法以及含钨废水中的处理方法,ZL 201810331940.7

[5] 曾坚贤,吕超强,周虎,郑柏树,董志辉,马溢昌,曾杰辉,一种离子印迹共混膜的制备方法,ZL 201810333720.8

研究方向

目前主要从事分子间弱相互作用理论计算、功能多孔材料设计合成以及能源环境相关气体吸附存储分离、多相催化等研究。